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Titanium (Ti) typically exhibits low mobility in geologic fluids due to the low aqueous solubility of common (Fe-)Ti oxide minerals. Consequently, Ti isotope variations (δ49/47Ti, given as δ49Ti) in geologic systems are primarily attributed to magmatic differentiation. Thus, the potential for fluid-mineral fractionation has received less attention. However, ligand-rich fluids are capable of mobilizing Ti as observed in natural systems and laboratory studies. As hydrothermal ore mineralization is commonly associated with ligand-rich brines capable of transporting significant quantities of metals, Ti isotopes may aid in understanding mineralization and alteration in complex hydrothermal systems. Here we present data from computational modeling of various Ti coordination complexes theorized to exist in geologic systems and/or under relevant experimental conditions as well as computed fractionation factors for various Ti-bearing crystalline phases to investigate the basic mechanics of equilibrium fluid-mineral Ti isotope fractionation. These results indicate that equilibrium fluid-mineral Ti isotope exchange between our modeled Ti complexes and phases with 6-coordinated Ti is predicted to generally lead to enrichment of heavy Ti isotopes in the fluid. Because minerals with 6-coordinated Ti (such as magnetite and ilmenite) are the most important reservoirs of Ti in the solid Earth, Ti isotope equilibration between terrestrial rocks and fluids can be generalized to enrich the fluid in heavy Ti isotopes. We also performed magnetite-ülvospinel leaching experiments to investigate fluid-mineral Ti isotope fractionation in this phase. Mineral leaching experiments varying acid strength, leaching temperature, and reaction time with HCl and HF qualitatively support the prediction that the fluid phase will become enriched in heavy Ti isotopes during fluid-mineral interactions that approach equilibrium with Ti-rich magnetite. Additionally, the leaching data also suggest that the fluid becomes slightly enriched in lighter Ti isotopes when Ti exchange is limited—potentially due to kinetic effects. Therefore, magnetite from natural systems may be depleted in heavy Ti isotopes during regenerative mineral replacement involving equilibration with fluids or may possibly become depleted in light Ti isotopes under a kinetic fractionation regime—leading to mineral δ49Ti values that are insufficiently explained by magmatic differentiation or inter-mineral fractionation. These results are a first look at fluid-mineral interactions that may affect Ti isotope fractionation in hydrothermal mineral systems, and Ti isotopes should be further studied as a potential method of understanding aqueous metal transport and tracing alteration in mineral deposits. 

We present MeerKAT H Iobservations of ESO 137-001, a quintessential jellyfish galaxy with long multi-phase tails formed due to the interaction with the intra-cluster medium of its host galaxy cluster, ACO 3627. Our observations reveal the presence of H Iin both the disc and outer regions of the galaxy for the first time, with a total H Imass of (3.5 ± 0.4)×10⁸M_⊙. ESO 137-001 is at an advanced stage of gas stripping; it is extremely H Ideficient and seems to have lost 90% of its initial H Imass; about 2/3 of the surviving H Iis found at larger radius than expected for a normal H Idisc and forms ∼40 kpc tail coincident with the tail detected at other wavelengths. Only ∼10% of the surviving H Iis still found within the stellar disc, consistent with the expectation of an outside-in truncation due to ram pressure. Similarly to other jellyfish galaxies, ESO137-001 has a high star formation rate for the low amount of H Idetected. We measure an H Idepletion time of 0.29 Gyr. However, when taking into account the total gas (H I+ H₂) content, the depletion time is consistent with typical values measured in nearby spiral galaxies. This suggests that ESO 137-001 is at its current stage of ram pressure interaction characterised by an efficient H Istripping, rather than an enhanced conversion of H Ito H₂, which was recently observed in some other jellyfish galaxies. 

Ram-pressure stripping of the spiral galaxy ESO 137−001 within the highly dynamical intracluster medium (ICM) of the Norma cluster lead to spectacular extraplanar CO, optical, Hα, UV, and X-ray emission. The Hαand X-ray tails extend up to 80 kpc from the galactic disk. We present dynamical simulations of the ram-pressure stripping event, and investigate the physics of the stripped gas and its ability to form stars. We also use these simulations to predict H Imaps and to constrain the orbit of ESO 137−001 within the Norma cluster. Special care was taken for the stripping of the diffuse gas. In a new approach, we analytically estimate the mixing between the intracluster and interstellar media. Different temporal ram-pressure profiles and the ICM-ISM mixing rate were tested. Three preferred models show most of the observed multiwavelength characteristics of ESO 137−001. Our highest-ranked model best reproduces the CO emission distribution, velocity for distances of ≲20 kpc from the galactic disk, and the available near-ultraviolet (NUV) observations. The second and third preferred models best reproduce the available X-ray and Hαobservations of the gas tail, including the Hαvelocity field. The angle between the direction of the galaxy’s motion and the plane of the galactic disk is between 60° and 75°. Ram-pressure stripping thus occurs more face-on. The existence of a two-tailed structure is a common feature in our models, and is due to the combined action of ram pressure and rotation together with the projection of the galaxy on the sky. Our modeling of the Hαemission caused by ionization through thermal conduction is consistent with observations. We predict the H Iemission distributions for the different models. Based on the 3D velocity vector derived from our dynamical model, we derive a galaxy orbit, which is close to unbound. We argue that ram pressure is enhanced by a factor of ∼2.5 compared to that expected for an orbit in an unperturbed spherical ICM. This increase can be obtained in two ways: an increase in the ICM density or a moving ICM opposite to the motion of the galaxy within the cluster. In a strongly perturbed galaxy cluster, such as the Norma cluster, with an off-center ICM distribution, the two possibilities are probable and plausible. 

Abstract We investigate the cold and warm gas content, kinematics, and spatial distribution of six local massive elliptical galaxies to probe the origin of the multiphase gas in their atmospheres. We report new observations, including Stratospheric Observatory for Infrared Astronomy [C ii ], Atacama Large Millimeter/submillimeter Array CO, Multi Unit Spectroscopic Explorer (MUSE) H α +[N ii ], and Very Large Array (VLA) radio observations. These are complemented by a large suite of multiwavelength archival data sets, including thermodynamical properties of the hot gas and radio jets, which are leveraged to investigate the role of active galactic nucleus (AGN) feeding/feedback in regulating the multiphase gas content. Our galactic sample shows a significant diversity in cool gas content, spanning filamentary and rotating structures. In our noncentral galaxies, the distribution of such gas is often concentrated, at variance with the more extended features observed in central galaxies. Misalignment between the multiphase gas and stars suggest that stellar mass loss is not the primary driver. A fraction of the cool gas might be acquired via galaxy interactions, but we do not find quantitative evidence of mergers in most of our systems. Instead, key evidence supports the origin via condensation out of the diffuse halo. Comparing with chaotic cold accretion (CCA) simulations, we find that our cool gas-free galaxies are likely in the overheated phase of the self-regulated AGN cycle, while for our galaxies with cool gas, the k-plot and AGN power correlation corroborate the phase of CCA feeding in which the condensation rain is triggering more vigorous AGN heating. The related C-ratio further shows that central/noncentral galaxies are expected to generate an extended/inner rain, consistent with our sample. 

Ascospores generated during sexual reproduction are the primary inoculum for the wheat scab fungus Fusarium graminearum. Purine metabolism is known to play important roles in fungal pathogens but its lifecycle stage-specific regulation is unclear. By characterizing the genes involved in purine de novo and salvage biosynthesis pathways, we showed that de novo syntheses of inosine, adenosine and guanosine monophosphates (IMP, AMP and GMP) are important for vegetative growth, sexual/asexual reproduction, and infectious growth, whereas purine salvage synthesis is dispensable for these stages in F. graminearum. Addition of GMP rescued the defects of the Fgimd1 mutant in vegetative growth and conidiation but not sexual reproduction, whereas addition of AMP rescued all of these defects of the Fgade12 mutant, suggesting that the function of de novo synthesis of GMP rather than AMP is distinct in sexual stages. Moreover, Acd1, an ortholog of AMP deaminase, is dispensable for growth but essential for ascosporogenesis and pathogenesis, suggesting that AMP catabolism has stage-specific functions during sexual reproduction and infectious growth. The expression of almost all the genes involved in de novo purine synthesis is downregulated during sexual reproduction and infectious growth relative to vegetative growth. This study revealed that F. graminearum has stage-specific regulation of purine metabolism during infectious growth and sexual reproduction. 

This proceeding was published in a special issue of J. Laser Appl. as: H. Cheng, C. Xia, S. M. Kuebler, P. Golvari, M. Sun, M. Zhang, X. Yu*. "Generation of Bessel-beam arrays for parallel fabrication in two-photon polymerization." J. Laser Appl. 2021, 33, 012040-1 - 012040-6; https://doi.org/10.2351/7.0000313. 

Abstract X-ray bursts are among the brightest stellar objects frequently observed in the sky by space-based telescopes. A type-I X-ray burst is understood as a violent thermonuclear explosion on the surface of a neutron star, accreting matter from a companion star in a binary system. The bursts are powered by a nuclear reaction sequence known as the rapid proton capture process (rp process), which involves hundreds of exotic neutron-deficient nuclides. At so-called waiting-point nuclides, the process stalls until a slower β + decay enables a bypass. One of the handful of rp process waiting-point nuclides is 64 Ge, which plays a decisive role in matter flow and therefore the produced X-ray flux. Here we report precision measurements of the masses of 63 Ge, 64,65 As and 66,67 Se—the relevant nuclear masses around the waiting-point 64 Ge—and use them as inputs for X-ray burst model calculations. We obtain the X-ray burst light curve to constrain the neutron-star compactness, and suggest that the distance to the X-ray burster GS 1826–24 needs to be increased by about 6.5% to match astronomical observations. The nucleosynthesis results affect the thermal structure of accreting neutron stars, which will subsequently modify the calculations of associated observables.